You can make Gecko code modifications in C for Super Mario Sunshine, and Super Mario Sunshine only, for now. (I'll probably make another kit for some other games in the future, though only me working on them; I don't want to involve Miluaces into the pain. ^ ^' )
First, you need to install devkitPro in order for your code to compile, and don't forget to set up the environment for devkitPPC. (Ex., C:\devkitPro\devkitPPC\bin) You can install the lib anywhere on your computer, as long as a folder in the file path doesn't contain any spaces. To compile your code, simply drag your C code file into build.bat.
That's good! The Gecko code should have automatically been copied to your clipboard. (Thanks Miluaces :D ) With that, you should now be able to paste that into your cheat code list in Dolphin and play your modification!
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More examples and updates to the lib will surely come at the right moment. Stick around in the IRC channel #sunshinerealm in irc.nolimitzone.com/6667 to meet and converse with the Sunshine Realm crew and see updates on current SMS modifications, big or small.